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Abstract
A new computationally assisted diagnostic to measure NO densities in atmospheric-pressure microplasmas by Optical Emission Spectroscopy (OES) is developed and validated against absorption spectroscopy in a volume Dielectric Barrier Discharge (DBD). The OES method is then applied to a twin surface DBD operated in N2 to measure the NO density as a function of the O2 admixture (0.1%–1%). The underlying rate equation model reveals that NO(A2Σ+) is primarily excited by reactions of the ground state NO(X2Π) with metastables N2(A3Σu+).
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