Determination of Nanoplastics Using a Novel Contactless Conductivity Detector with Controllable Geometric Parameters.

Abstract

Plastic waste in the environment is continuously degraded to form nanoplastic particles, and its harm has attracted widespread attention. At present, the identification and quantification of nanoplastics are performed by visual observation and using some spectroscopy methods, which are time-consuming and lack accuracy. Therefore, this study proposes a contactless conductivity detector (C4D) based on a glass microfluidic chip with controllable geometric parameters to quantify nanoplastics. We found that when the insulating layer thickness was 15 μm, the electrode spacing was 1 mm, and the shielding method was on-chip shielding, the detector displayed the best performance. The detector possesses a simple structure with high sensitivity and outstanding reproducibility, that is, the limit of detection of KCl solutions can reach the micromolar level, and the intraday RSD is 0.2% (n = 5). This work uses a microfluidic chip C4D to study nanoplastics for the first time, and the limit of detection is 0.25 μg/mL and the quantitative limit is 0.8 μg/mL. In addition, plant experiments have verified that terrestrial plants can absorb nanoplastics in water, expanding the application of contactless conductivity detectors and providing a new method for the quantitative analysis of nanoplastics.