Abstract
Photoacoustic calorimetry has been used to determine the M-H mean bond dissociation energies in Ru(dmpe) 2 H 2 (dmpe=Me 2 PCH 2 CH 2 PMe 2 ) and H 2 IrCl(CO)(PPh 3 ) 2 (63.5±2.0 and 64.0±1.0 kcal mol -1 , respectively). The quantum yield for loss of H 2 from the ruthenium dihydride complex has been measured by transient actinometry as 0.85±0.05. Ru(dmpe) 2 is an unsolvated intermediate and reacts with CO and N 2 to form Ru(dmpe) 2 CO and Ru(dmpe) 2 N 2
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