Abstract
AbstractIntegral, isothermal heat‐of‐condensation values for continuously generated vapors of various constant‐composition mixtures, along with the isothermal densities of the condensates, enable the calculation of the cohesive energy densities of solutions. Data for the complete range of composition of the chloroform‐acetone system and for a major portion of the chloroformdiethyl ether system at 35°C are reported. From these data, the specificinteraction‐energy density for each system is calculated, based upon an extension of the Scatchard‐Hildebrand Regular Solution Theory.The essential equality of the specific‐interaction energy‐density values for the two systems indicates a preponderance of the same kind of hydrogen bonding (CH‐‐‐O) in each.
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