Abstract
A method for digestion of plastics from waste of electrical and electronic equipment (WEEE) was developed using the microwave-assisted wet digestion in single reaction chamber (MAWD-SRC). The determination of As, Cd, Co, Cr, Cu, Ni, Pb, Sb and Zn by inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma optical emission spectrometry (ICP OES) was carried out after sample digestion. Mercury was determined by flow-injection cold vapor generation coupled to inductively coupled plasma mass spectrometry (FI-CVG-ICP-MS). Results obtained using MAWD-SRC for sample preparation were compared with those obtained using microwave-assisted wet digestion (MAWD) at high pressure. Acid mixtures (HNO3 or HNO3 + HCl) were evaluated and feasibility for further inorganic contaminants determination by ICP-MS and ICP OES was demonstrated. Sample preparation by MAWD-SRC using HNO3 + HCl mixture resulted in better digestion efficiency in comparison to MAWD. In addition, lower limits of quantification were obtained using MAWD-SRC due to the higher sample mass that can be digested (500 mg). The combination of HNO3 and HCl for digestion showed to be crucial for quantitative recovery of some elements, as Cr and Sb. Agreement with certified values was better than 96%.
Highlights
The rapid replacement of electrical and electronic equipment (EEE) by other with better technology has contributed to the increasing amount of waste electrical and electronic equipment (WEEE).[1,2] In addition to the environmental impact, has been of concern the presence of hazardous substances in these WEEE, such as heavy metals and brominated flame retardants (BFRs).[3]
No statistical difference (t-test, 95% confidence level) was observed for all analytes for results obtained by microwave-assisted wet digestion (MAWD)‐Single Reaction Chamber (SRC) and MAWD. These results show that both methods can be considered suitable options for sample preparation of WEEE for further determination of inorganic contaminants, including those required in RoHS Directive
ICP OES: inductively coupled plasma optical emission spectrometry; ICP-MS: inductively coupled plasma mass spectrometry; FI‐CVG-ICP-MS: flow-injection cold vapor generation coupled to ICP-MS; MAWD-SRC: microwave-assisted wet digestion in single reaction chamber
Summary
The rapid replacement of electrical and electronic equipment (EEE) by other with better technology has contributed to the increasing amount of waste electrical and electronic equipment (WEEE).[1,2] In addition to the environmental impact, has been of concern the presence of hazardous substances in these WEEE, such as heavy metals and brominated flame retardants (BFRs).[3]. It is important to point out that by using MAWD-SRC a higher sample mass can be digested, improving LOQs and a lower residual carbon in digest is obtained.
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