Determination of Gaseous and Particulate Secondary Amines in the Atmosphere Using Gas Chromatography Coupled with Electron Capture Detection

Abstract

The aim of this study was to develop and optimize methods for the determination of gaseous and particulate (PM2.5) secondary amines (SAs) in the atmosphere using gas chromatography coupled with electron capture detection (GC-ECD) following chemical derivatization. The methods employed the liquid–liquid extraction (LLE) of pentafluorobenzenesulfonyl derivatives of the SAs before analytical samples were injected into GC-ECD. The optimized methods were applied to the determination of SAs in gaseous and particulate samples at two sites (urban and rural areas) from June to September in 2021. Gaseous samples were collected into an SPE cartridge containing a mixture of silica gel and sulfamic acid at a flow rate of 2 L·min−1 for 48 h. Particulate samples were collected onto 47 mm filters by a cyclone sampler at a flow rate of 16.7 L·min−1 for 48 h. The linearity of calibration curves, accuracy, and precision of the methods were satisfactory. In most of the field samples, dimethylamine (DMA), methylethylamine (MEA), diethylamine (DEA), and dipropylamine (DPA) were found to be the most frequently encountered compounds at the sampling sites.