Determination of fouling mechanisms in polymeric ultrafiltration membranes using residual brines from table olive storage wastewaters as feed

Abstract

In this work, the fouling mechanisms that dominate the ultrafiltration of residual brines from table olive packing plant wastewaters were investigated. For that purpose, Hermia's models adapted to crossflow filtration, resistance-in-series model and a model combining intermediate blocking and cake formation mechanisms were fitted to the experimental data. Tests were performed with a 5 kDa polyethersulfone membrane at transmembrane pressures between 1 and 3 bar and crossflow velocities between 2.2 and 3.7 m s−1. Results demonstrated that the resistance-in-series model was the most accurate to predict permeate flux evolution with time. The predominant fouling mechanism was cake formation followed by intermediate blocking/adsorption. The fouling resistances that were determined by means of the resistance in series model were tested using a well-established mathematical model proposed by Mondal and De that also combines both fouling phenomena (intermediate pore blocking and cake formation). Results demonstrated that the predicted resistances are consistent with those determined by Mondal and De's model.