Abstract

A flow concept is developed to measure fast gas–liquid reaction kinetics based on a tube-in-tube reactor.

Highlights

  • The determination of gas–liquid reaction kinetics is often performed with a stirred cell reactor by recording the pressure decay over time with no analysis of the liquid phase.[10,11] This method is simple to operate and widely applied

  • To demonstrate the accuracy and efficiency of this automated platform for reaction kinetics determination, we considered two case studies: absorption of CO2 into aqueous methyl diethanolamine (MDEA) (Scheme 1) and ozonolysis of propionaldehyde (Scheme 2)

  • The reaction kinetics of CO2 with aqueous MDEA are well described in the literature using different techniques.[33,34,35]

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Summary

Introduction

The determination of gas–liquid reaction kinetics is often performed with a stirred cell reactor by recording the pressure decay over time with no analysis of the liquid phase.[10,11] This method is simple to operate and widely applied. This model is used to determine the kinetic reaction rate from gas uptake data at various liquid flow rates.

Results
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