Abstract

A general computer program for calculating the parameters in generalized and phenomenological spin-Hamiltonians from experimental EPR data is described. The program is completely general and can be employed to solve any secular matrix equation. The algorithm makes use of symmetry properties to achieve rapid and efficient convergence. The program will analyze EPR data sets consisting of any number of transition frequency-applied magnetic field pairs obtained at any combination of frequencies, applied magnetic fields, magnetic field-crystal symmetry axis orientations, and ΔM = ±1, ±2,… transitions.

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