Abstract
Unless the area of an inlaid disc electrode is sufficiently large, and/or the scan rate fast enough, the ‘plateau’ of a semiintegrated d.c. voltammogram or aperiodic component of an a.c. voltammogram has a slope. This phenomenon, which has its origin in non-planar diffusion at the edge of the disc, interferes with an otherwise efficient method of determining diffusion coefficients. Methods of circumventing this difficulty are presented and tested with simulated and experimental data.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
