Abstract
The result of an isotopic exchange reaction is expressed in terms of the isotopic abundance ratios, the fractionation factor and the atom number ratio of the reactants. The general formula is applied to the CO 2 -H 2 O system and simplified by neglecting terms small in relation to the experimental crror. The influence of variations in the experimental parameters on the equilibrium is discussed. It is found that changes in temperature as well as atom number ratio will influence the equilibration process appreciably.
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