Abstract
AbstractSolutions of various concentrations of tetramethylammonium chloride and trimethylammonium chloride in liquid hydrogen chloride have been examined by Raman spectroscopy and the solvation number of Cl− anions in these solutions determined. It was found for solutions up to 3 mol I−1 of (CH3)4N+Cl− in liquid HCl, that the Cl− anions are solvated by six HCl molecules, while trimethylammonium chloride exists in the form of ion pairs solvated by five HCl molecules, (CH3)3N+H ⃛Cl−, 5HCl.
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