Deterioration of dynamic fracture properties of granite under the coupled effects of hydrochemical solutions and freeze-thaw cycles

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Fractured rock mass is a kind of complex rock mass widely existing in engineering projects, which is often subjected to erosion by different pH hydrochemical solutions such as surface water, acid rain, acidic and alkaline wastewater discharge, and deicing salts. When the rock project in a cold region suffers from the coupled effects of hydrochemical solutions and freeze-thaw (FT) cycles, the frost-heave-thaw-shrinkage characteristics of rocks are different from ordinary FT under dynamic loads, and the effect of FT cycles may be enlarged or reduced in different hydrochemical solutions. How to determine the effect of FT cycles on the expansion and changes of rock fractures, which is related to the safety and stability of many engineering rock masses in cold regions. In this study, the microstructure changes of specimens induced by hydrochemical solutions and cyclic FT were measured using nuclear magnetic resonance (NMR) and X-ray diffraction (XRD). The dynamic fracture tests were conducted using single cleavage triangle (SCT) granite specimens. Crack propagation gauge (CPG) was applied to examine crack propagation speed (CPS). The findings indicate that the mineral composition of the granite did not vary large with the hydrochemical solutions and FT cycles, but the maximum diffraction intensity of each mineral composition changed. For the granite under the coupling effect of hydrochemical solutions and FT cycles, the granite specimen in NaOH solution with 100 FT cycles has the highest dynamic fracture toughness and is 10.76 MPa·m1/2, dynamic fracture toughness of H2O, HNO3 and Na2SO4 solutions are only 0.94, 0.91 and 0.93 of that of NaOH solution. With increasing FT cycle times, the dynamic fracture toughness and crack speed decrease, whereas the porosity increases. For the specimen in NaOH solution and 100 FT cycles, dynamic fracture toughness decreased by 18.12 % without FT cycles and crack speed decreased by 34.18 %, the porosity increases by 26.42 %.