Abstract
This study investigates the residual chemical composition of waterlogged archaeological lignocellulosic material found in Greece. Hazelnut pericarps and oak wood found in a 16th‐century wreck, along with endocarps of olives dated at 300 bc, were examined. 13C CP/MAS NMR was applied to compare fresh and waterlogged archaeological materials. Results show qualitative alterations in their composition. The virtual absence of peaks at ~21 ppm and ~173 ppm, corresponding to hemicelluloses in all archaeological materials, indicates that these constituents can be an important indicator in assessing the type and degree of deterioration.
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