Abstract
The present contribution is devoted to the analysis of three extremely weak A-type bands of 16O3 recorded near 7686, 7739 and 7860cm−1i.e. only a few % below the dissociation limit, D0, at about 8560cm−1. They correspond to the most excited vibration–rotation states of ozone observed so far via high-resolution absorption spectroscopy. They were detected by high sensitivity CW-cavity ring down spectroscopy with a typical noise equivalent absorption, αmin, on the order of 2×10−10cm−1 and modelled using the effective operator approach. The derived band centres and rotational constants show a very good agreement with recent theoretical predictions based on a new ab initio potential energy surface.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Quantitative Spectroscopy and Radiative Transfer
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
