Abstract
A dynamic micro-kinetic model is developed in close agreement with all the details of the NO2-related SCR catalytic chemistry over a Cu-zeolite catalyst. The rate parameters are estimated from transient kinetic runs, namely isothermal concentration step changes, temperature programmed desorption (TPD) and temperature programmed surface reaction (TPSR) experiments, designed to address the individual steps in the surface mechanism, including adsorption of ammonia, adsorption of NO2 in the form of surface nitrites and nitrates, decomposition of nitrites to nitrogen via reaction with ammonia, reversible reduction of nitrates to nitrites by NO (Fast SCR route), and direct reduction of nitrates by ammonia (NO2-SCR route). The fitted set of rate equations is able to predict the complex transient behaviors associated with the global Fast-SCR and NO2-SCR reactions observed in T-ramp validation experiments.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
