Abstract
The kinetics of the generation of the net chemically induced dynamic electron polarization (CIDEP) in triplet-radical quenching (TRQ) in liquids is theoretically analyzed in detail. The method of treatment of non-adiabatic transitions between states of the TR spin hamiltonian which determine the TRQ is proposed. Analytical formulas are derived for the CIDEP-generation probability Pe and rate Ke, as well as for the TRQ probability Pq and rate Kq. It is shown that the dependence of Ke on the relative diffusion coefficient Dr is often non-monotonic, and this dependence cannot be correctly described by the usually applied relation Ke=KqPe.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
