Abstract

Abstract A set of equivalent positions in an achiral skeleton is regarded as an orbit as-signed to a coset representation G(/Gi), where the subgroup Gi is Cnv or Cn. Desymmetrization of the achiral skeleton by substituting a single ligand is examined by virtue of the subduction of the coset representation G(/Gi) ↓ Gi, which is determined to be αGi(/Gi) + βGi(/Gk(i)). The multiplicities (α and β) of the resulting coset representations are calculated from the data of the participating groups and the normalizer of Gi.

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