Abstract
1-(Phenylsulfinyl)-1-(tributylstannyl)cyclopropane on treatment with acyl chlorides or alkyl chloroformate in refluxing dichloromethane afforded 1-acyloxy-1-phenylsulfenyl- and 1-alkoxycarbonyloxy-1-phenylsulfenylcyclopropanes, respectively. The reaction involves the Pummerer-type rearrangement with loss of tributylstannyl group.
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