Abstract
Ab initio (6-31G* and MP3/6-31G*//6-31G*) calculations show that vinyl cations substituted with α-CN, α-CHO and α-CF 3 groups are by 15–18 kcal/mol less stable than their saturated analogues and are among the least stable carbenium ions generated to date via solvolysis.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.