Desorption of crystal violet from alkali-treated agricultural material waste: an experimental study, kinetic, equilibrium and thermodynamic modeling

Abstract

PurposeThis paper aims to focus on studying the batch desorption of adsorbed crystal violet (CV) from date stones (Phoenix dactylifera), untreated (UDS) and treated using NaOH (TDS).Design/methodology/approachThe process variables such as different desorbing agents, volume and concentration of the desorbing agent, contact time, dye concentration before adsorption and temperature affecting CV desorption from CV-loaded untreated date stones (CV@UDS) and treated adsorbent (CV@TDS) were optimized. The UDS and TDS were regenerated using 0.6 m HCl as eluent.FindingsThe HCl solution was an excellent eluent for the CV desorption from CV@UDS (96.45%) and CV@TDS (98.11%). The second-order model and the Langmuir model well exemplified experimental data with maximum desorption capacities were 63.29 mg g−1 for the CV@UDS and 243.90 mg g−1 for the CV@TDS. The calculated thermodynamic showed that the CV desorption was spontaneous, endothermic and physical. Good regeneration and reusability of UDS and TDS for the CV removal for four consecutive adsorption–desorption cycles.Practical implicationsThis study provided a good example of reusing UDS and TDS with NaOH for fast removal of a toxic organic pollutant, CV from the wastewaters.Originality/valueThe use of UDS and TDS with NaOH for the first time for desorption study and their reusability to removing CV from their aqueous solutions.