Designing sustainable membrane-based water treatment via fouling control through membrane interface engineering and process developments

Abstract

Membrane-based water treatment processes have been established as a powerful approach for clean water production. However, despite the significant advances made in terms of rejection and flux, provision of sustainable and energy-efficient water production is restricted by the inevitable issue of membrane fouling, known to be the major contributor to the elevated operating costs due to frequent chemical cleaning, increased transmembrane resistance, and deterioration of permeate flux. This review provides an overview of fouling control strategies in different membrane processes, such as microfiltration, ultrafiltration, membrane bioreactors, and desalination via reverse osmosis and forward osmosis. Insights into the recent advancements are discussed and efforts made in terms of membrane development, modules arrangement, process optimization, feed pretreatment, and fouling monitoring are highlighted to evaluate their overall impact in energy- and cost-effective water treatment. Major findings in four key aspects are presented, including membrane surface modification, modules design, process integration, and fouling monitoring. Among the above mentioned anti-fouling strategies, a large part of research has been focused on membrane surface modifications using a number of anti-fouling materials whereas much less research has been devoted to membrane module advancements and in-situ fouling monitoring and control. At the end, a critical analysis is provided for each anti-fouling strategy and a rationale framework is provided for design of efficient membranes and process for water treatment.