Designing Carbonized Loofah Sponge Architectures with Plasmonic Cu Nanoparticles Encapsulated in Graphitic Layers for Highly Efficient Solar Vapor Generation.

Abstract

Solar vapor generation represents a promising approach to alleviate water shortage for producing fresh water from undrinkable water resources. Although Cu-based plasmonics have attracted tremendous interest due to efficient light-to-heat conversion, their application faces great challenges in the oxidation resistance of Cu and low evaporation rate. Herein, a hybrid of three-dimensional carbonized loofah sponges and graphene layers encapsulated Cu nanoparticles is successfully synthesized via a facile pyrolysis method. In addition to effective light harvesting, the localized heating effect of stabilized Cu nanoparticles remarkably elevated the surface temperature of Cu@C/CLS to 72 °C, and a vapor generation rate as high as 1.54 kg m-2 h-1 with solar thermal efficiency reaching 90.2% under 1 Sun illumination was achieved. A study in the purification of sewage and muddy water with Cu@C/CLS demonstrates a promising perspective in a practical application. These results may offer a new inspiration for the design of efficient nonprecious Cu-based photothermal materials.