Abstract
Oxidative addition of halogens to tetracyanoplatinate results in the formation of a Pt(iv)-building block that, combined with Cu(ii), forms coordination polymers Cu(H2O)2[PtX2(CN)4] (X = Br, Cl). These materials exhibit directional anisotropic thermal expansion: nearly zero expansion within the cyanometallate sheets and positive thermal expansion in the third dimension.
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