Abstract
We systematically examine the effect of nonmetal vacancy on the lattice parameter of four materials including TiC, TiN, ZrC and ZrN by first-principles calculations. Based on their results, we design a type of material Ti0.19Zr0.81N1-x that keeps the lattice volume nearly constant within a wide nitrogen-vacancy concentration 0 < x < 0.3 and reveal the underlying origin of the vacancy-independent lattice volume. Ti0.19Zr0.81N1-x samples with different nitrogen-vacancy concentrations are synthesized successfully by reactive spark plasma sintering and their lattice parameters measured by X-ray diffraction confirm the theoretical prediction. This kind of material is hopeful to show high dimensional stability in nuclear irradiation conditions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
