Abstract

We describe the fabrication and properties of flexible, anisotropic silver nanorod sheets and investigate their potential to function as a sensor. Aligned and tilted silver nanorod (AgNR) arrays are incorporated into polydimethylsiloxane (PDMS) to form flexible conductive sheets. The electrical properties of these sheets are investigated and show large anisotropies, which are related to the alignment direction of the nanorods. Notably, the films show the greatest electrical resistance in the direction perpendicular to the nanorod alignment, and when strain is applied along this direction, the resistance increases monotonically with increasing loading/unloading cycles. In comparison, the resistance along the nanorod alignment direction remains constant over many strain cycles and therefore can serve as an internal reference or as a stable strain gauge. These changes in resistivity are attributed to changes in the internanorod connectivity and can be modeled using an effective medium approximation for aniso...

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