Abstract

This paper deals with the design, operation, modeling, and grid integration of bioelectrochemical systems (BES) for power-to-gas application, through an electromethanogenesis process. The paper objective is to show that BES-based power-to-gas energy storage is feasible on a large scale, showing a first approximation that goes from the BES design and operation to the electrical grid integration. It is the first study attempting to cover all aspects of a BES-based power-to-gas technology, on authors’ knowledge. Designed BES reactors were based on a modular architecture, suitable for a future scaling-up. They were operated in steady state for eight months, and continuously monitored in terms of power consumption, water treatment, and biomethane production, in order to obtain data for the following modeling activity. A black box linear model of the BES was computed by using least-square methods, and validated through comparison with collected experimental data. Afterwards, a BES stack was simulated through several series and parallel connections of reactors, in order to obtain higher power consumption and test the grid integration of a real application system. The renewable energy surplus and energy price variability were evaluated for the grid integration of the BES stack. The BES stack was then simulated as energy storage system during low energy price periods, and tested experimentally with a real time system.

Highlights

  • The International Energy Agency (IEA) fixed the objective of reducing CO2 emissions by 50% before 2050, compared to 2005 values [1]

  • The paper objective is to show that bioelectrochemical system (BES)-based power-to-gas energy storage is feasible on a large scale, showing a first approximation that goes from the BES design and operation to the electrical grid integration

  • The efficiency and cost of the system are out of the scope of this paper, and they will be studied in future works

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Summary

Introduction

The International Energy Agency (IEA) fixed the objective of reducing CO2 emissions (related with energy generation) by 50% before 2050, compared to 2005 values [1]. This challenge requires the development and implementation of renewable energy plants, CO2 capture, and usage (CCU). The extensive integration of renewables into the electrical system comes with the need of energy storage and backup systems, to secure continuity in the production and distribution of electricity. An innovative power-to-gas technology, based on a bioelectrochemical system (BES), was developed for renewable energy surplus storage in the form of biomethane (Figure 1). The biomethane can be obtained from biogas by different upgrading systems, being water scrubbing the most common one

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