Abstract
Here, we have designed a functional dialysis membrane with a catalase pseudoactive center on the surface. To make the catalase pseudoactive center, we have modified the regenerated cellulose dialysis membrane with methylated or octylated poly(1-vinylimidazole) (PVIm-Me or PVIm-Oc), followed by manganese or iron tetrakis(4-carboxyphenyl)porphyrin (Mn- or Fe-TCPP), using the layer-by-layer (LbL) method. As a result of the optimization, the dialysis membrane modified with 25 mol % methylated poly(1-vinylimidazole) [PVIm-Me(25)] and Mn-TCPP produced the highest amount of oxygen (O2) from hydrogen peroxide (H2O2) without the decomposition of Mn-TCPP. Conversely, Mn- and Fe-TCPP were decomposed under other experimental conditions in the presence of H2O2. These results suggest the conversion of H2O2 to O2 by catalase catalytic activity on the surface coated with PVIm-Me(25) and Mn-TCPP.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Langmuir : the ACS journal of surfaces and colloids
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
