Abstract

AbstractThe three‐dimensional microporous Ti‐based MOF material MIL‐125‐NH2 (MIL: Material of Institut Lavoisier) was successfully used as a support for palladium nanoparticles designed as catalysts for p‐nitrophenol hydrogenation. According to the mild and green synthetic approach, two catalysts of different nanoparticle morphology and different catalytic activity were obtained. Enhanced catalytic activity was found for a catalyst prepared using KBr as a capping agent, while Pd NPs of undefined shape synthesized without KBr were less active.

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