Abstract
AbstractChiral peptidyl thiourea organocatalysts were designed and synthesized for asymmetric ring‐opening of cis‐stilbene oxides with N‐phenylpiperazines. Chiral β‐amino alcohols were obtained with up to 95 % ee after crystallization. The configuration at the N‐terminal residue stereogenic center of peptidyl thiourea organocatalyst was found to affect the stereochemical outcome of the reaction.
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