Design of PAMAM grafted chitosan dendrimers biosorbent for removal of anionic dyes: Adsorption isotherms, kinetics and thermodynamics studies

Abstract

PAMAM grafted chitosan as biocompatible adsorbent was synthesized through Michael addition of methyl acrylate followed by amidation of ethylenediamine on the chitosan backbone. Then, the adsorption capacity of bioadsorbents were assessed by employing two anionic dyes. The adsorption experiments were carried out using a batch adsorption system. The influence of various operational variables such as different PAMAM generations, pH, adsorbent dosage, contact time, initial dye concentration and temperature on the maximum adsorption capacity (qm) were investigated. The adsorbent consists of second generation of PAMAM (CS-PAMAM G2) demonstrated high removal efficiency for both dyes. The maximum adsorption capacity of CS-PAMAM G2 for Congo Red at certain operational conditions was 559.3 mg/g; while the maximum adsorption capacity for Amido Black 10B at certain operational conditions was 489.8 mg/g; which revealed endothermic and exothermic nature of adsorption process for Congo Red and Amido Black 10B, respectively. These results were then well confirmed by thermodynamics studies. Also, kinetic studies showed that the dye adsorption process followed a pseudo-second-order kinetic model. Moreover, among various applied isotherms, the experimental data were well-fitted by Sips model. Consequently, CS-PAMAM G2 showed superior potential for the removal of dyes from aqueous phase.