Design of novel Al-Mg-(Zn-Sc) alloys with enhanced mechanical properties and corrosion resistance

Abstract

The novel Al-Mg-(Zn-Sc) alloys were fabricated using vacuum induction melting and argon-protected casting method. The effects of Zn and Sc on the microstructure evolution, mechanical properties and corrosion properties of the as-cast Al-Mg-(Zn-Sc) alloys were comparatively studied. The results show that the addition of 1.5 wt% Zn facilitates the evolution of coarsen β-Al3Mg2 phases into fine T-Mg32(Al, Zn)49 phases, enhancing the resistance to intergranular corrosion (IGC) of Al-5.5Mg-1.5Zn-0.4Sc (alloy 4) with a maximum corrosion depth of 133.4 µm. The addition of Zn also promotes Mg solid solution, resulting in a 13.7 % increase in Mg solid solution concentration in Al-5.5Mg-1.5Zn (alloy 3) compared to Al-5.5Mg (alloy 2). The addition of 0.4 wt% Sc leads to the formation of smaller (∼2 µm) Al3Sc particles with a larger volume fraction of 0.96 %, providing grain refinement and improved strength in the Al-Mg alloy. Furthermore, the joint addition of Zn and Sc elements reduces the grain size by 64.0 % compared to Al-5.0Mg (alloy 1) and increases the tensile strength by 33.5 %. Alloy 4 exhibits the greatest measured tensile strength of 343 MPa. The solid solution strengthening, grain boundary strengthening and precipitation strengthening contributions to alloy 4 are calculated at 76.8 MPa, 27.9 MPa and 66.6 MPa, respectively.