Design of nearly perfect hyperuniform polymeric materials.

Abstract

Disordered hyperuniform materials are exotic amorphous systems that simultaneously exhibit anomalous suppression of long-range density fluctuations, comparable in amplitude to that of crystals and quasi-crystalline materials, while lacking the translational order characteristic of simple liquids. We establish a framework to quantitatively predict the emergence of hyperuniformity in polymeric materials by considering the distribution of localized polymer subregions, instead of considering the whole material. We demonstrate that this highly tunable approach results in arbitrarily small long-range density fluctuations in the liquid state. Our simulations also indicate that long-ranged density fluctuation of the whole polymeric material is remarkably insensitive to molecular topology (linear chain, unknotted ring, star, and bottlebrush) and depends on temperature in an apparently near universal fashion. Our findings open the way for the creation of nearly perfect hyperuniform polymeric materials.