Abstract
AbstractHerein, we report the synthesis and characterization of two ruthenophane (1) and ruthenium(II)‐π (2) complexes, and the results of their catalytic applications under different conditions. These complexes exhibited excellent air and moisture stability due to the existence of effective cation‐π interactions between the metal ion and the aromatic surface of the ligand. These complexes were tested and compared in the transfer hydrogenation of acetophenone in 2‐propanol. The ruthenophane complex 1 exhibited highest efficiency in the catalytic transfer hydrogenation reaction when compared to the complex 2.The better efficiency of the complex 1 can be ascribed to the steric and cation‐π interactions of the cyclophane ligands with the metal centre under reaction conditions. Using catalyst loading of ca. 2 mol%, the transfer hydrogenation of the aromatic ketones having different substituents was achieved. Notably, these complexes exhibited high selectivity for the aromatic ketones having electronegative substituents and showed highest efficiency of ca. 100% under moderate reaction conditions when compared to the literature known ruthenium catalysts.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
