Abstract
In this paper, we report the design and synthesis of La3+ based high-entropy pyrochlore ceramics (HEPCs) with five different B-site cations using the valence combination strategy. The factors affecting the formation of pyrochlore phase have been investigated. The result reveals that both valence disorder and size disorder can significantly affect the formability of pyrochlore phase, and the formability increases as the two disorders decrease. Following this guideline, a set of new HEPCs with single phase have been successfully synthesized.
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