Abstract
We have designed and prepared novel diphosphine ligands bearing an Os(tpy)22+ moiety as a light-harvesting unit and have found that these diphosphine ligands coordinate to the rhodium atom in a bidentate manner. The rhodium complexes including diphosphine ligands bearing an Os(tpy)22+ moiety have been revealed to work as an effective photocatalyst for the production of dihydrogen.
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