Design and Synthesis of Cobalt-Based Hollow Nanoparticles through the Liquid Metal Template.

Abstract

Co-based compounds have attracted much attention due to their competitive catalytic activities. To enhance their intrinsic electrocatalytic activity, morphology engineering is one of the effective strategies. Hollow structures have fascinating properties due to their low density and high loading capacity. In this work, we introduce a Ga-based liquid alloy as a reactive template for the synthesis of varying Co-based hollow nanoparticles. The fluidity character of the Ga-based liquid alloy facilitates the large-scale production of nanoparticles via a top-down shearing process. The pre-installed active species (here is Zn) in the liquid alloy serve as a sacrificial source to quantitatively reduce Co2+ ions and form Co-based compounds. Well-structured Ga/CoOOH core-shell nanospheres are thus successfully prepared, and more varied Co-based hollow nanoparticles can be obtained by post-treatment and reaction. Hollow structures can offer enhanced interfacial area and increased active sites, benefiting the catalytic performance. Among the prepared Co-based catalysts, CoSe2 hollow nanoparticles exhibited the best oxygen evolution reaction (OER) activity with an overpotential of 340 mV at the current density of 10 mA/cm2. This work provides a novel strategy for the rational design and simple preparation of hollow nanoparticles.