Abstract
A novel series of near infrared heptamethine indocyanine dyes bearing various aromatic chromophores has been synthesized. The synthetic methodology was achieved via ester condensation reactions of heptamethine indocyanine parent dye with carboxylic moiety and aromatic compounds such as anthracene, pyrene and thiophene derivatives. Structural analysis of the newly prepared dyes was accomplished using one- and two-dimensional nuclear magnetic resonance, infrared spectroscopy and electrospray ionization mass spectrometry. These dyes exhibited high molar absorptivity based on the UV–visible/near-infrared spectral data. Fluorescence emission spectral data was used to determine the relative quantum yield. The new dyes displayed formation of H-aggregates in water at low concentrations, while this behavior was not observed in methanol.
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