Design and simulation of highly efficient CZTS/CZTSSe based thin-film solar cell

Abstract

Thin-film solar cells are a substitute for more common crystalline silicon solar cells, which consist of thin semiconductor layers. Thin-film materials comprise direct bandgap and can absorb sunlight more efficiently than silicon. In this article, a double-absorber-based thin-film solar cell comprising CZTS/CZTSSe is designed and optimized through numerical simulation. The proposed solar cell structure consists of a transparent window layer made of aluminum-doped zinc oxide, followed by an intrinsic zinc oxide layer, an n-type cadmium sulfide layer, and a p-type combined absorber layer of copper zinc tin sulfide (Cu2ZnSnS4) (CZTS) and copper zinc tin sulfur-selenium alloy (Cu2ZnSn(S,Se4)) (CZTSSe). The structure is further optimized by introducing two interfacial layers between CZTSSe/CZTS and CZTS/CdS. The highest conversion efficiency is achieved by adjusting the thicknesses of the layers, the doping densities in different layers, and the defect densities in the two absorber layers. The optimized model, with a total thickness of 2.01 μm, demonstrates an open-circuit voltage (Voc) of 0.7669 V, a short-circuit current (Jsc) of 48.57740 mA/cm2, a fill factor (FF) of 70.61%, and efficiency (η) of 26.31%. These results suggest that CZTS is a promising candidate for replacing other thin-film photovoltaic materials, such as CdTe. The proposed double-absorber thin-film solar cell optimizes doping concentration, thickness, and defect density to enhance performance metrics and efficiency while utilizing non-toxic materials to promote cost-effective, environmentally friendly energy solutions.