Design and performance boost of a MOF-functionalized-wood solar evaporator through tuning the hydrogen-bonding interactions

Abstract

Interfacial solar evaporation technology is recognized as one of the most promising strategies to address freshwater scarcity issues. To realize the sustainability of this technology for producing potable water from seawater and contaminated water sources, multi-functional photothermal materials need to be explored to attain higher vapor output at the same solar energy input. Herein, a novel wood-based solar evaporator composed of porous wood substrate, zeolitic imidazolate framework-8 (ZIF-8), and polydopamine (PDA) as a light absorption layer is developed. The in-situ loading of ZIF-8 in the microchannels renders the wood evaporator an important function of reducing the equivalent evaporation enthalpy due to the lowered hydrogen bonding density of water molecules when they pass the wood channels, substantially augmenting solar evaporation efficiency. A superior evaporation rate of 2.70 kg m−2 h−1 is achieved under 1.0 sun irradiation, which exceeds the theoretical limit of a typical 2D photothermal evaporator (~1.46 kg m−2 h−1). The designed wood/ZIF-8@PDA also exhibits a prominent removal efficiency for harmful ions and organic pollutants. This multifunctional wood-based solar evaporator shows great potential for future freshwater production.