Abstract

Alkaline electrolysis systems are currently considered to be suitable for large-scale hydrogen production. Previous research has primarily focused on integrating renewable energy sources such as solar and wind into water electrolysis systems. However, intermittent issues stemming from the sporadic nature of renewable energy sources have led to the introduction of energy storage systems (ESSs) to address these intermittent challenges. Extensive research has been conducted on the efficiency and operational aspects of these systems. In contrast to other renewable energy sources, hydropower offers the advantages of stable output and high utilization, making it a promising solution for overcoming intermittent issues. In this study, we propose the design of an optimized alkaline electrolysis system tailored for small-scale hydropower generation. This approach allowed us to confirm the efficiency of a small-scale hydropower-based hydrogen production facility and the analysis of hydrogen production costs under diverse scenarios. Notably, the optimal selling price per kilogram of hydrogen was determined to be USD 15.6 when the operational time exceeded 20 h, albeit indicating a challenging market supply. Under the consideration of various scenarios and government subsidies, this study revealed that a USD 10/kgH2 subsidy or 24 h of continuous operation achieved break-even points in the sixth and eighth years, respectively. Ultimately, the findings underscore the necessity for essential measures, including government backing and technological advancements in small-scale hydropower facilities, to enhance the economic viability of the green hydrogen market in South Korea.

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