Design and manufacture of lead-free eco-friendly cement-based piezoelectric composites achieving superior piezoelectric properties for concrete structure applications

Abstract

A complex-ion doping strategy fabricates lead-free BCZT ceramic. The excellent properties (d33 ∼ 577 pC/N, Kt ∼ 52%, TC ∼ 110 °C, d∗33 ∼ 620 pm/V, εr ∼ 1820, tanδ ∼ 0.02) were obtained in BCZT ceramic. The in-situ Raman spectroscopy and PFM were conducted to reveal the mechanisms for the superior properties achieved. BCZT ceramics were manufactured for cement-based piezoelectric composites, including 0–3, 2-2 and 1–3 types. 0–3 type (50% BCZT) showed the properties (d33 ∼ 46 pC/N, εr ∼ 310 and Kt ∼ 18.1%). 2-2 and 1–3 types exhibited good piezoelectric properties (d33 ∼ 285 pC/N, εr ∼ 720 and Kt ∼ 33.4% for 2-2 type; d33 ∼ 238 pC/N, εr ∼ 485 and Kt ∼ 29.5% for 1–3 type). Temperature-dependent electrical properties of BCZT-cement composites were systematically explored. Additionally, BCZT ceramic was designed and fabricated for PCD vibration energy harvesting. The output voltage (∼4.9 V) and output power (∼2.4 mW) were obtained. This work underpins the significance of lead-free BCZT ceramic and cement-based piezoelectric composites, and promotes their applications in smart structures.