Abstract
The applications of inorganic micromaterials as enzyme-like catalysts are receiving much attention owing to high efficiency, stability, and low cost. However, few reports have focused on the structure and applications of peroxidase mimic in organic reactions. Herein, we have synthesized an enzyme-like iron hydrogen phosphate crystal with a unique micro-flower hierarchical structure following a controllable low-temperature hydrothermal process by self-assembling, and we used as a catalyst in the oxidation reactions for the first time. The peroxidase mimic with new morphology exhibited excellent enzyme-like catalytic performance in the oxidation of benzyl alcohol by H2O2. This catalyst has higher catalytic activity and better stability at specific temperature and pH ranges than natural peroxidases.
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