Design and control concept of a 1 MWth chemical looping gasifier allowing for efficient autothermal syngas production

Abstract

Chemical looping gasification (CLG) is a novel gasification concept, allowing for the efficient production of a high calorific, N₂-free syngas with low tar content. Previous studies showed that the inherent process characteristics require a dedicated process control concept in order to allow for sufficient solid and thus heat transport between the two reactors (air and fuel reactor) of the gasification unit, while at the same time being able to accurately tailor the air-to-fuel equivalence ratio (λ), thus obtaining stable gasification conditions. To demonstrate its viability, a suitable control concept was implemented in the 1 MWth modular pilot plant located at the Technical University Darmstadt. In this paper, results obtained during the first ever autothermal CLG operation, achieved in this unit using biomass pellets as the feedstock, are presented, highlighting important process fundamentals. It is demonstrated that the novel process control concept allows for an accurate control of λ in semi-industrial scale, while at the same time guaranteeing stable hydrodynamics and thus solid and heat transport between the air and fuel reactor, making it a suitable control concept for large-scale implementation. Moreover, it is demonstrated that the underlying phenomena of the CLG process lead to substantial system inertia, as the solid bed inventory of the gasifier acts as an oxygen storage during transient periods, evoked by changes in the air-to-fuel equivalence ratio.