Abstract
AbstractThe solvatochromic shift of the most intensive band of fluorenone radical anion (FN*‐) in the visible region has been examined in 10 polar formally aprotic media. It has been found that this shift depends on the solvent acceptor number (AN) and static dielectric constant (D) according to planar regression: It is suggested that the ground state of FN*‐ is relatively stabilized in a solvent with a high acceptor number and the dipole moment of the solute increases during an excitation.
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