Derivation of porous cellulose propionate using hydrated hydroxyl groups and hydraulic pressure

Abstract

This study aimed to enhance the thermal stability of microporous separators by introducing cellulose propionate (CP) as an innovative polymer matrix material, supplemented with glycerin as an additive. CP/glycerin composite membranes were created using hydraulic pressure techniques to reinforce essential separator properties. SEM analysis unveiled interconnected pores crucial for efficient ion transport, initiating water flux measurements at 5 bar. These measurements showcased improved mechanical strength, resulting in a porosity of 74.1 %. FT-IR spectroscopy illustrated CP-glycerin interactions, inducing plasticization and facilitating pore formation. Thermal Gravimetric Analysis (TGA) demonstrated superior thermal stability in CP/glycerin composite membranes compared to cellulose acetate (CA). Differential Scanning Calorimetry (DSC) revealed a slight reduction in thermal stability within a specific temperature range due to glycerin-induced plasticization effects. Nonetheless, the melting temperature (Tm) of CP/glycerin membranes increased to 188.4 °C, indicating heightened stability at elevated temperatures. Despite pressure-induced pore formation, CP/glycerin membranes exhibited enhanced thermal stability, suggesting reinforced molecular interactions. Overall, this study introduces a novel CP/glycerin composite membrane featuring improved thermal stability, enhanced strength, and controlled pore structures essential for efficient lithium-ion battery applications.