Abstract

A new form of Memory Function (MF) appearing in the Mori's formalism has been derived using plausible approximations. In addition to the fact that present form of MF satisfies sum-rules upto sixth order, it has special characteristic of presence of one more adjustable parameter. It is also found that the present form of MF behaves as sech v (bt) under suitable conditions. The utility of the present MF is exemplified by studying time evolution of velocity auto correlation function and transport coefficients of Lennard–Jones fluids.

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