Abstract
One approach to asymmetric homoaldol reactions may be provided by the surprising finding that the lithium compound 1 racemizes only very slowly at − 78°C. Compound 1 reacts with ClTi(Net2)3 with inversion to give a species that can add to carbonyl compounds with 1,3-chirality transfer.
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More From: Angewandte Chemie International Edition in English
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