Depositional and diagenetic controls on hydrocarbon generation of mudstones through clay–organic matter interactions: A comparative study of the Dongpu Depression, Bohai Bay Basin, China

Abstract

Although the hydrocarbon generation of mudstones is greatly affected by depositional and diagenetic environments, how they affect the integrated theoretical framework of organic matter (OM) preservation, mudstone formation, and OM diagenetic conversion remains unresolved. Therefore, we addressed this issue from the perspective of clay–OM interactions during mudstone formation and diagenetic evolution. The northern and southern Dongpu Depressions represent two endmembers of depositional (weak vs. strong hydrodynamics and abundant vs. limited terrigenous input) and diagenetic (saline vs. freshwater pore fluid) environments. Results highlighted that the protection of clay minerals on OM preservation was more affected by the depositional fabric than mineral content. For the northern Depression mudstones, the predominance of laminated mudstones and remarkable enrichment of high-hydrogen index OM in the clay-sized fractions indicated the intimate clay-OM associations during mudstone formation, which led to better OM preservation and a higher hydrocarbon generation potential. For the southern Depression mudstones, the scattered distribution of OM particles and inconspicuous OM enrichment in the clay-sized fractions coincided with lower hydrocarbon generation potential. Additionally, the faster smectite illitization accelerated by the saline environment of the northern Depression led to OM desorption. Thus, OM lost the protection of clay minerals and the mineral reactive sites were liberated, both of which were beneficial to hydrocarbon generation. Generally, deposition controlled the material premise and diagenesis determined the hydrocarbon generation impetus. These findings provide a theoretical reference for shale oil accumulation in saline lacustrine systems and can potentially serve as a guide for future oil–gas exploration and development.