Abstract
A mixed-valent Fe(II)Fe(III) complex was deposited at the surface of cationic monolayers by photoirradiation of the aqueous subphase containing equimolar Fe 3+ and Fe(CN) 3− 6 ions. The photo-deposition process was detected in situ by the measurement of reflectance spectra at the air-water interface at a constant surface pressure. The present technique provides a first example of the photo-induced mineralization process at the air-water interface.
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